Shooting down an ace squadron will reward the player with a medal after completion of the level. Once every medal has been obtained, the Aircraft Viewer will be available in the Options menu.
Note that the Z.O.E. aces will appear in succession, and the next Z.O.E. plane will appear only after its predecessor is shot down. For example, if you fail to shoot down the F-14 Z.O.E. in the Sledgehammer mission, the F-14 will appear again in the Seagull mission. In order to face the ADF-01 Z.O.E. ace in the Fighter's Honor mission, the player must defeat every Z.O.E. in the first mission each one appears in.

Mission 2: Easy Money
1 x F-4E "Superfly"
Mission 4A: Tin Castle
1 x MiG-29 "Ricochet"
Mission 4B: Opera House
2 x Su-25 "D-Cowboy"
Mission 6A: Midnight Assassin
2 x F-117A "Razorback"
Mission 6B: Bear Tracks
2 x F-117A "Razorback"
Mission 7: Sledgehammer
1 x F-14A "Z.O.E." (Captain)
Mission 9: Swordsmith
1 x F-16C "Tallman"
1 x F-16 "Metal Sphere"
Mission 10: Toy Box
1 x MiG-31 "Stalker"
Mission 11: Seagull
2 x R-MO1 "Hangmen"
1 x F/A-18E "Z.O.E." (Major)
Mission 13: Power Play
1 x YF-22 "Z.O.E." (Colonel)
Mission 14A: El Dorado (Alphaville branch)
1 x Tornado F.3 "Max"
1 x Tornado F.3 "Goose"
Mission 14B: Dark Star (Bellissima branch)
3 x EF-200 "Death Rave 2000"
Missoin 15A: St. Elmo's Fire (Alphaville branch)
1 x F-15E "Xiao"
1 x F-15E "Jian"
1 x F-15E "Dao"
Mission 15B: Dead End (Bellissima branch)
4 x YF-23A "Fox Force Four"
Mission 19: Kingpin
1 x F-15S "Z.O.E." (General)
Mission 21: Fighter's Honor
1 x ADF-01 "Z.O.E." (Commander)
SOURCES
Ace Combat 2 (In-game data)
ACCREDITATION
Original article by tkgamer
MenAce for the medals

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